河北省奥陶纪马家沟组顶部古风化壳中三稀元素赋存状态及富集机制     

杨鑫朋  张运强  程洲  杨瑞  季虹  张欢  石光耀  王金贵 《矿床地质》2023,42(1):157-169

河北省奥陶纪马家沟组与晚石炭世本溪组之间发育一套古风化壳层,岩性主要为铁质黏土岩、铝质黏土岩和铝土岩,剖面从顶到底具典型的“煤-铝-铁”结构。地球化学分析结果显示,冀东石岭和冀南同义岭古风化壳样品的轻稀土元素氧化物总质量分数分别达0.0893%和0.0717%,均超过了古风化壳型轻稀土矿边界品位,冀北煤窑山古风化壳样品的轻稀土元素总质量分数为0.0504%,也具明显富集特征。古风化壳中部分样品稀有元素Li含量也超过了伴生边界品位。通过元素逐级分离试验定量分析出古风化壳中的三稀元素主要以矿物相存在,再通过X射线衍射分析、电子探针分析进一步确定三稀元素主要以类质同象赋存于伊利石、高岭石等黏土矿物中,少量以化合态存在于独立的稀土矿物中。综合分析认为,古风化壳中三稀元素的矿化富集依次经历了风化壳形成阶段、铝质岩系形成阶段及沉积压实阶段的多阶段演化。  相似文献   

贵州遵义二叠纪锰矿地球化学特征与沉积环境分析：以遵义谢家坝富锰矿床为例     

陈登 《地质与勘探》2023,59(4):691-703

为分析贵州遵义二叠纪锰矿的沉积环境,对谢家坝锰矿床进行常量元素、微量和稀土元素地球化学研究。研究认为：谢家坝锰矿赋存于茅口组顶部含锰岩系中,可分为下矿层豆状、角砾状菱锰矿、似层状菱锰矿,以及上矿层碎屑状、块状菱锰矿的二元结构矿石类型组合,可广泛代表遵义锰矿的矿石特征。谢家坝锰矿上下矿层之间主量元素和稀土元素含量差异较大,常量元素SiO2、TiO2、S、Fe2O3含量上矿层均大于下矿层,MnO、MgO与 Al2O3之间均呈负相关关系;上矿层Fe/Mn值较高,属高Fe低P型锰矿,而下矿层Fe/Mn值较低,属中低Fe低P型锰矿。上矿层稀土元素PAAS标准化配分后呈现较明显的重稀土亏损、弱的轻稀土富集、右倾配分的特征,具有弱的Ce正异常,类似海底铁锰结核稀土元素特征;下矿层呈现弱的中稀土富集,轻、重稀土亏损,弱的帽式分配特征,具明显的Ce负异常,类似典型深部海水沉积稀土元素特征。微量元素Th/U、Ni/Co、V/Cr、V/（V+Ni）、AU等沉积环境古氧相分析指标和稀土元素PAAS标准化配分模式指示,谢家坝锰矿下矿层是在贫氧-厌氧条件下Mn2+与CO32-直接形成菱锰矿,上矿层在常氧-贫氧环境下Mn3+、Mn4+以氧化物或氢氧化物形式沉淀。  相似文献   

滇西澜沧黑河地区超高压变质岩中金红石微量元素特征     

吕伟 《地质与勘探》2023,59(6):1260-1270

为研究黑河地区金红石微量元素特征及榴辉岩型金红石矿床的成矿地质条件,本文选取滇西澜沧黑河地区榴辉岩、石榴多硅白云母片岩中的金红石进行LA-ICP-MS微量元素分析。结果表明金红石微量元素呈现阶梯式三级分布特征,最富集Nb、Ta,其次是Zr、Hf,含量较少的元素有Ba、Rb、Sr、Th、REE;榴辉岩、榴闪岩类原岩属于变质基性岩类,含蓝晶石榴闪岩原岩属于玄武质凝灰岩类,石榴多硅白云母片岩类原岩属于泥质岩类;榴辉岩中金红石Nb/Ta比值均要高于其全岩Nb/Ta比值,金红石Nb、Ta含量与变质作用过程中元素在各矿物间的分配系数有关;采用金红石Zr含量温度计获得黑河地区榴辉岩的峰期变质阶段金红石形成温度为578～605℃,峰期变质作用后的退变质流体会造成金红石中Zr的再平衡。此外,黑河地区具备榴辉岩型金红石矿床形成的成矿物源、成矿作用的物理化学条件以及成矿的物质基础,有一定的找矿潜力。  相似文献   

中国萤石矿床分类及稀土元素地球化学特征     

刘道荣 《地质与勘探》2023,59(2):211-222

中国萤石资源丰富,矿床数量众多,但尚无统一的分类标准。在总结现有萤石矿床分类基础上,以成矿热液来源为依据,将单一型萤石矿床划分为岩浆期后热液型、火山-次火山热液型及热卤水型3种,并介绍了各类萤石矿床的主要地质特征。结合已有文献资料,总结归纳各类型萤石矿床的稀土元素组成特征,探讨了成矿热液演化过程。岩浆期后热液型矿床萤石具有较高的稀土总量(∑REE均值约70×10^-6)、较显著的铕负异常(δEu峰值在0.6～0.7)和较小的Y/Ho比值(主要变化范围30～65);火山-次火山热液型矿床萤石稀土总量与岩浆期后热液型接近,但具有显著的铕负异常或弱-中等的铕正异常(δEu峰值分别在0.1～0.2和1.1～1.2)和较小的Y/Ho比值(集中在40～50);热卤水型矿床萤石具有较低的稀土总量、显著的铕正异常(平均δEu>2)及较大的Y/Ho比值(均值约83)。与岩浆期后热液型和火山-次火山热液型矿床相比,热卤水型矿床的成矿流体可能经历了更复杂的演化过程。  相似文献   

Reconstruction of the Yangtze Ramp during Floian to Darriwilian (Ordovician) in South China: Its Morphology, Controlling Factors and Significances     

LUAN Xiaocong  André DESROCHERS  WU Rongchang  LIU Jianbo  WANG Guangxu  LIANG Yan  ZHANG Yuchen  WEI Xin  LI Lixi  ZHAN Renbin 《《地质学报》英文版》2023,97(6):1756-1777

A robust stratigraphic framework and a coherent depositional ramp model for the Zitai, Dawan, Meitan and Ningkuo formations of Floian–Darriwilian age (Early–Middle Ordovician) in the Yangtze (Daoba, Xiangshuidong, Daling, Gudongkou and Honghuayuan sections) and Jiangnan regions (Nanba section) was created based on lithofacies and major element analysis. Three siliciclastic (LF1–3) and six carbonate (LF4–9) lithofacies are recognized representing sediments that were deposited in mixed siliciclastic and carbonate ramp environment. The intensity of mixed sedimentation and terrigenous input were evaluated using the elemental proxies Intensity of Mixed sedimentation (IM) and Aluminum Accumulation Rate (AlAR), as well as their mean values during certain time intervals. Mixed sediments are most well-developed along the marginal Yangtze region, strongly impacted by recurrent influx of westerly derived terrigenous materials in response to global eustatic changes and regional tectonic movements, shaping the gently southeast-dipping morphology. Regular terrigenous influx resulted in periods of enhanced primary productivity on the Yangtze Ramp as evidenced by matching biodiversity peaks in planktonic organisms, i.e., chitinozoans and acritarchs. Brachiopods and other shelly fauna were also able to proliferate as new niches developed along the gently dipping ramp floor with substrate changes. The biodiversification patterns suggest that terrigenous influx controlled in part by regional tectonics played a more important role than previously thought in the development of Great Ordovician Biodiversification Event in South China.  相似文献   

Deformation induced decoupling between U-Pb and trace elements in titanite revealed through petrochronology and study of localized deformation     

《地学前缘(英文版)》2023,14(2):101496

In this contribution, we analyzed a pair of mafic samples collected from a recently identified shear zone and its proximal footwall from the Manicouagan Imbricate Zone (MIZ) of the central Grenville Province, Québec, Canada. Titanite petrochronology, metamorphic phase equilibria modelling, trace element thermometry, and electron backscattered diffraction data were used to define a Pressure-Temperature-time-Deformation path for the two samples. An interconnected dislocation network within titanite grains, as outlined with Kerneled Average Misorientation maps, are spatially correlated with variation in the U-Pb system but not with that observed for trace element These results suggest that the U-Pb system was decoupled from trace and rare earth elements and that deformation, rather than interface-coupled dissolution-precipitation reactions or re-crystallisation, was the main driver for this decoupling. In addition to highlighting a potential pitfall of titanite petrochronology, our P-T-t-D path reveals that ductile shear zones were active later than previously suggested within the MIZ.  相似文献   

New insights into the multiple magmatic fluid generations from scheelite in the Bastielieke W-polymetallic deposit,Chinese Altay (NW,China)     

《地学前缘(英文版)》2023,14(3):101532

Scheelite is the main ore mineral in skarn-type tungsten (W-Mo, W-Sn, and W-Cu) deposits, and is also a good proxy for ore-fluid evolution and mineralization. The Bastielieke deposit is the first medium-size W-polymetallic skarn deposit discovered in the Chinese (Xinjiang, NW China) Altay. Scheelite grains at Bastielieke are distributed in biotite granite, skarn and quartz-fluorite veins. They exhibit different textures, and can be divided into four types and six subtypes, including those in granite (Schm), prograde skarn (SchI), retrograde-altered rocks (SchII), and those in late-stage quartz-fluorite veins (SchIII).SchIa and SchIb were formed in the early and late prograde stage, respectively. SchI displays homogeneous texture, enrichments of light rare earth elements (LREEs) relative to heavy REEs (HREEs), and significantly negative Eu anomalies. SchIa has higher Sr-Mo contents and LREE/HREE than SchIb. SchII shows patchy texture by overgrowth and dissolution-reprecipitation, and can be subdivided into dark (SchIIa) and light (SchIIb) zone based in CL imaging. All SchII grains are LREE-enriched with negative Eu anomalies and relatively low LREE/HREE ratios. SchIIb has much higher W-Mo-Nb-Sr contents than SchIIa, which is ascribed to late-stage hydrothermal modifications. Schm and SchIII display homogeneous texture and similar MREE-enriched patterns, as well as very low Mo-W-Sr and different Nb contents.The texture and compositional variations in Bastielieke scheelites reveal that two magmatic fluids derived from different granitic magma reservoirs were involved in the mineralization. The earlier ore-fluid is relativly oxidized and has low HREE contents, forming the early prograde skarn-stage mineralization. Episodic influxes of later F-rich granitic magmatic fluids may have modified the earlier scheelite compositions, leading to multistage W enrichment and varying intragrain compositions.  相似文献   

2016年冬季京津冀豫大气污染的时空分布及影响因子研究     

江琪  王飞  张恒德  吕梦瑶  何佳宝 《气象》2019,45(5):695-704

利用2016年12月至2017年2月北京、天津、石家庄和郑州的PM2.5质量浓度、反应性气体质量浓度及其相对应的气象要素资料分析了大气污染的理化特征、传输和生消规律。结果表明:北京、石家庄、天津及郑州的PM2.5质量浓度分布频率均有两个较为明显的峰值,四个地区PM2.5质量浓度分布频率最高时均值分别为10.1、19.2、40.0和47.1μg·m^-3,大气的氧化程度为北京最低,其次为石家庄、天津,郑州最高。四个研究地区的交通源对环境大气污染均有重要贡献。PM2.5和CO的相关性在低相对湿度时高于高相对湿度时;而PM2.5和NO2的相关性在相对湿度较大时高于相对湿度较小时。四个研究地区的PM2.5质量浓度均随风速的增大呈快速降低后趋于平缓的趋势,其中北京、石家庄和郑州的风速阈值均为3m·s^-1,天津地区为4m·s^-1。受上游污染地区的影响,偏南风的输送作用滞后20~30h达到最大,而偏北风的影响作用在滞后8~12h达到最大。  相似文献   

闽中梅仙丁家山铅锌矿床硫化物微量元素地球化学特征及其成矿意义   总被引：1，自引：1，他引：0  

石得凤  陈冬生  朱云  李桂贤  张德贤  刘洋  杨仙  鲁玉龙 《矿床地质》2021,40(3):432-448

梅仙丁家山铅锌矿床是闽中新元古代马面山群中多个大中型铅锌多金属矿床的典型代表.本文以丁家山铅锌矿床两类矿石(含磁黄铁矿矿石和含磁铁矿矿石)内的闪锌矿和黄铁矿为研究对象,通过电子探针及LA-ICP-MS微量元素分析技术,揭示二者的微量元素组成和赋存状态,探讨成矿温度及矿床成因方面的重要信息.分析结果显示:闪锌矿内Fe、Mn、Cd、Cu、In、Pb、Bi元素较为富集,两类矿石内的闪锌矿除Fe元素含量相差较大以外(平均值分别为9.3％和1.7％),其他元素含量并无明显差异;电子探针面扫描和LA-ICP-MS剥蚀图像显示元素Mn、Cd、In以类质同象形式存在,而Fe、Cu、Pb、Bi则有类质同象和显微包体2种存在形式.黄铁矿微量元素含量整体较低,元素Co、Ni、Pb、Bi相对富集,Ni、Mn主要以类质同象形式存在,Cu、Co有类质同象替换和显微包体2种形式,Pb、Bi主要以方铅矿包体形式存在.两类矿石中的闪锌矿Zn/Cd比值分别在120～150之间和93～210之间,均指示中温成矿条件.两类闪锌矿内Fe、Cd、Mn元素含量特征与典型矽卡岩型矿床内的闪锌矿相吻合;矿床内硫化物硫同位素组成揭示成矿物质来自于岩浆岩.上述证据共同支持梅仙丁家山铅锌矿矿床属矽卡岩型矿床.  相似文献   

黔西北普宜地区下三叠统嘉陵江组沉凝灰岩锆石LA- ICP- MS U- Pb年龄、微量元素特征     

缪宇  吴亮  肖长源  李锁明  李致伟  宋文婷  田瑜峰 《地质论评》2021,67(1):67020002-67020002

早三叠世时期频繁的火山事件是导致全球性气候和海洋环境异常的主要原因,前人对早三叠世重要界线时期的火山事件地层开展了大量研究,但对典型界线时期以外的其他火山事件地层却鲜有报道。本文以上扬子西南普宜地区嘉陵江组两件沉凝灰岩为研究对象开展了岩石学、岩相学、锆石年代学及微量元素组合特征等方面的研究。沉凝灰岩样品具有典型岩浆锆石的内部结构和微量元素组合特征,两组沉凝灰岩锆石谐和年龄分别为250. 6±0. 6 Ma和249. 1±0. 8 Ma,代表了母岩岩浆中新生锆石的结晶年龄。沉凝灰岩母岩主要以酸性花岗岩类为主,次为中性正长岩类和少量基性岩类。嘉陵江组沉凝灰岩与二叠系—三叠系界线(PTB)凝灰岩及Olenekian—Anisian界线(OAB)绿豆岩具有同源性,形成于活动大陆边缘的碰撞造山环境,源区很可能位于中越边境地区长山构造岩浆带—十万大山火山带,且在陆壳碰撞过程中源区地壳处于持续的增厚阶段,下地壳增厚部位的部分熔融形成补给岩浆上涌并使早期结晶矿物发生了部分熔蚀。本文嘉陵江组沉凝灰岩样品250. 6±0. 6 Ma年龄对应着Smithian—Spathian界线时期的全球性降温及短期生物复苏事件;249. 1±0. 8 Ma年龄的样品对应Spathian亚阶中期极端高温气候和生物再次灭绝事件,再次证明了早三叠世时期频繁的火山活动是导致气候改变和生物周而复始新生和灭绝的重要因素。其原因可能是阳伞效应和温室效应等因素综合反馈的结果,但具体证据仍需要将来更多学科综合研究成果的约束。  相似文献